A team of researchers from the University of Nottingham’s School of Chemistry and Faculty of Engineering recently published the results from research in which they were able to turn metal waste into a catalyst for hydrogen production.

The researchers found that the surface of swarf, a byproduct of the metal machining industry, is textured with tiny steps and grooves on a nanoscale level. These textures can anchor atoms of platinum or cobalt, leading to an efficient electrocatalyst that can split water into hydrogen and oxygen. The research has been published in the Journal of Material Chemistry A.

Hydrogen seen as a clean fuel to gasoline or diesel powered vehicles or for heating as the only byproduct of its combustion is water vapor. However, most hydrogen production methods rely on fossil fuel feedstock. Electrolysis of water is one of the most promising green pathways for hydrogen production, as it only requires water and electricity.

The researchers used magnetron sputtering to create a platinum atom “rain” on the swarf’s surface. These platinum atoms then come together into nanoparticles that fit snugly into the nanoscale grooves.

Dr. Madasamy Thangamuthu, a Postdoctoral Researcher at the University of Nottingham who was responsible for the analysis of the structure and electrocatalytic activity of the new materials, says, “It is remarkable that we are able to produce hydrogen from water using only a tenth of the amount of platinum loading compared to state-of-the-art commercial catalysts.

“By spreading just 28 micrograms of the precious metal over 1 cm² of the swarf, we were able to create a laboratory-scale electrolyzer that operates with 100% efficiency and produces 0.5 liters of hydrogen gas per minute just from a single piece of swarf.”

The group is partnering with AqSorption Ltd, a Nottingham-based company specializing in electrolyzer design and fabrication to scale up their technology. Professor Andrei Khlobystov, School of Chemistry, University of Nottingham, said, “The electrocatalysts made from swarf have the potential to greatly impact the economy. Our unique technology developed at Nottingham, which involves atom-by-atom growth of platinum particles on nanotextured surfaces, has solved two major challenges.

“Firstly, it enables the production of green hydrogen using the least amount of precious metal possible, and secondly, it upcycles metal waste from the aerospace industry, all in a single process.”

The Zero Carbon Cluster has been set in the East Midlands to accelerate the development and deployment of innovation in green industries and advanced manufacturing.

Professor Tom Rodden, PVC for Research & Knowledge Exchange at the University of Nottingham said, “Developing hydrogen propulsion systems can be a significant step towards addressing some of the world’s most pressing zero-carbon challenges, especially for the transport and manufacturing industries. However, this strategy’s success depends on producing green hydrogen sustainably, such as through water splitting via electrolysis, and this, in turn, requires advancements in materials design.”

Source: University of Nottingham